There are some shows that need a while to find their footing....and then there are those that just hit the right note from the very start. I have loaned out my set of VM DVDs more times than I can count, and I've never had to say to anyone, "Just give it a chance and it will grow on you after a few episodes." Nope. In every case, my friends were hooked with the very first episode. Now, on the other hand, I have had to tell my friends, "Be patient with Logan. He'll melt your heart eventually."
I like episode 1 for so many reasons, but among the tops are: The chemistry between Veronica and her Dad, cleaver exposition and set up of each of the main characters, an intriguing plot arch that grabbed me from the start.